Place the fresh pineapple chunks, coconut water, lime juice, and Bacardi Superior rum into a high-speed blender.
Add the ice to the blender container.
Secure the lid and blend on high speed for 20-30 seconds until the mixture is completely smooth and frothy.
Taste for sweetness and add a drop of liquid stevia if a sweeter profile is desired.
Pour the contents into a chilled glass.
Garnish with a fresh pineapple wedge and serve immediately.